The author of 《MOF nano porous-supported C-S cross coupling through one-pot post-synthetic modification》 were Alinezhad, Heshmatollah; Ghasemi, Shahram; Cheraghian, Mansoureh. And the article was published in Journal of Organometallic Chemistry in 2019. Recommanded Product: 624-31-7 The author mentioned the following in the article:
UIO-66-NH2-Fu@Ni was synthesized by anchoring a mol. nickel furfural (Fu) complex into a functionalized nanoporous metal-organic framework (MOF) with the amine functional groups, using the one-pot post-synthetic modification. This new catalyst was identified via Fourier-transform IR (FT-IR) spectroscopy, proton-nuclear-magnetic-resonance (1HNMR) spectroscopy, nitrogen gas adsorption-desorption method, thermogravimetric analyses (TGA), energy-dispersive X-ray- mapping spectroscopy (EDX-MAP), field emission SEM (FE-SEM), and X-ray diffraction (XRD). 1HNMR anal. showed that around 16% of the amine functional groups of the nanocrystalline UIO-66-NH2 framework were modified with nickel complex. Also, according to the inductive couple plasma at. emission spectroscopy (ICP), around 2.98 w% of Ni was determined in the modified MOF. The Ni complex which was supported by UIO-66-NH2 nanocatalyst was effectively used as a heterogeneous catalyst for the formation of sulfur-containing mols. such as thioethers which are generally found in chem. biol., organic synthesis, and materials chem. through the C-S bond cross-coupling of aryl iodides with thiols. UIO-66-NH2-Fu@Ni propagated the condensation reaction by different aryl iodides and aryl thiols in moderate conditions in the presence of K2CO3 as a base in high reaction yield during 8-14 h. The Ni complex which was supported by UIO-66-NH2 nanocatalyst was simply recycled and reused thrice while its catalytic activity was maintained approx. In the experimental materials used by the author, we found 1-Iodo-4-methylbenzene(cas: 624-31-7Recommanded Product: 624-31-7)
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Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com