In 2022,Salardon, Noemi; Otarola, Guillermo; Manas, Clara; Merino, Estibaliz; Batanero, Belen published an article in Journal of Environmental Chemical Engineering. The title of the article was 《Electrochemically driven one-pot oxidative conversion of arylhydrazines into aromatic iodides》.SDS of cas: 90-14-2 The author mentioned the following in the article:
The efficient metal-free electrosynthesis of aryl iodides ArI [Ar = Ph, 4-OMeC6H4, 1-naphthyl, etc.] was here reported starting from aryl hydrazines. Surprisingly this dinitrated arylhydrazine minimized, under the applied exptl. conditions, any anodic multilayered film formation. This sustainable iodide-mediated oxidative dehydrazination enabled coupling reaction of electrogenerated iodine with aryl radicals from electron-deficient arylhydrazines employing electricity as the driving force and an inexpensive halogen source. A mechanistic proposal explaining the formation of aryl iodides was presented and discussed. In the part of experimental materials, we found many familiar compounds, such as 1-Iodonaphthalene(cas: 90-14-2SDS of cas: 90-14-2)
1-Iodonaphthalene(cas: 90-14-2) is one of organic iodides. Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs. Oceanic alkyl iodides are believed to be the principal source of atmospheric iodine.SDS of cas: 90-14-2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com