《Gold-Catalyzed 1,2-Diarylation of Alkenes》 was published in Angewandte Chemie, International Edition in 2020. These research results belong to Chintawar, Chetan C.; Yadav, Amit K.; Patil, Nitin T.. HPLC of Formula: 624-31-7 The article mentions the following:
Herein, the authors disclose the gold-catalyzed 1,2-diarylation of alkenes through the interplay of ligand-enabled AuI/AuIII catalysis with the idiosyncratic π-activation mode of gold complexes. Unlike the classical migratory-insertion-based approach to 1,2-diarylation, the present approach not only circumvents the formation of direct Ar-Ar’ coupling and Heck-type side products but more intriguingly demonstrates reactivity and selectivity complementary to those of previously known metal catalysis (Pd, Ni, or Cu). Detailed studies to underpin the mechanistic scenario revealed oxidative addition of aryl iodides to an AuI complex to be the rate-limiting step owing to the non-innocent nature of the aryl alkene. After reading the article, we found that the author used 1-Iodo-4-methylbenzene(cas: 624-31-7HPLC of Formula: 624-31-7)
1-Iodo-4-methylbenzene(cas: 624-31-7) undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid catalyzed by (Ni,Mg)3Si2O5(OH)4 solid-solution nanotubes loaded with palladium.HPLC of Formula: 624-31-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com