The author of 《Water-mediated C-H activation of arenes with secure carbene precursors: the reaction and its application》 were Nie, Ruifang; Lai, Ruizhi; Lv, Songyang; Xu, Yingying; Guo, Li; Wang, Qiantao; Wu, Yong. And the article was published in Chemical Communications (Cambridge, United Kingdom) in 2019. Application of 1774-47-6 The author mentioned the following in the article:
A water-mediated C-H activation using sulfoxonium ylides was reported, providing a general, green and step-economic approach to construct a C-C bond and varieties of useful N-heterocycle scaffolds. Three series of aryl-alkylketones RCOCH2R1 [R = t-Bu, 1-adamantanyl, Ph; R1 = 2-(2-pyridyl)phenyl, 2-(2-pyridyl)-3-thienyl, 2-pyrazol-1-ylphenyl, etc.], benzothiazines I [R2 = Me, i-Pr, Ph, Bn; R3 = i-Pr, t-Bu, Ph; R4 = H, 6-Me, 6-OMe, 6-F, 8-OMe] and isoquinolines II [R5 = H, 8-F, 6-Br, etc.; R6 = H, Me; R7 = 2,6-di-MeOC6H3, 2-naphthyl, 2-thienyl, etc.] were synthesized via rhodium-catalyzed coupling of arenes/sulfoximines/benzylamines with sulfoxonium ylides. In the part of experimental materials, we found many familiar compounds, such as Trimethylsulfoxonium iodide(cas: 1774-47-6Application of 1774-47-6)
Trimethylsulfoxonium iodide(cas: 1774-47-6) is a sulfoxonium salt. It is used to generate dimethyloxosulfonium methylide by reaction with sodium hydride. The latter compound is used as a methylene-transfer reagent, and is used to prepare epoxides.Application of 1774-47-6
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com