Pike, Sebastian D.; White, Edward R.; Regoutz, Anna; Sammy, Nicholas; Payne, David J.; Williams, Charlotte K.; Shaffer, Milo S. P. published an article about the compound: Mesitylcopper(I)( cas:75732-01-3,SMILESS:[Cu]C1=C(C)C=C(C)C=C1C ).SDS of cas: 75732-01-3. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:75732-01-3) through the article.
Exceptionally small and well-defined copper (Cu) and cuprite (Cu2O) nanoparticles (NPs) are synthesized by the reaction of mesitylcopper(I) with either H2 or air, resp. In the presence of substoichiometric quantities of ligands, namely, stearic or di(octyl)phosphinic acid (0.1-0.2 equiv vs. Cu), ultrasmall nanoparticles are prepared with diameters as low as ∼2 nm, soluble in a range of solvents. The solutions of Cu NPs undergo quant. oxidation, on exposure to air, to form Cu2O NPs. The Cu2O NPs can be reduced back to Cu(0) NPs using accessible temperatures and low pressures of hydrogen (135 °C, 3 bar H2). This striking reversible redox cycling of the discrete, solubilized Cu/Cu(I) colloids was successfully repeated over 10 cycles, representing 19 sep. reactions. The ligands influence the evolution of both composition and size of the nanoparticles, during synthesis and redox cycling, as explored in detail using vacuum-transfer aberration-corrected transmission electron microscopy, XPS, and visible spectroscopy.
After consulting a lot of data, we found that this compound(75732-01-3)SDS of cas: 75732-01-3 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com