The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Mesitylcopper(I)( cas:75732-01-3 ) is researched.HPLC of Formula: 75732-01-3.Suzuki, Yuta; Yazaki, Ryo; Kumagai, Naoya; Shibasaki, Masakatsu published the article 《Direct catalytic asymmetric intramolecular conjugate addition of thioamide to α,β-unsaturated ester》 about this compound( cas:75732-01-3 ) in Chemistry – A European Journal. Keywords: indenethiocarboxamide enantioselective preparation; thioamide unsaturated ester asym intramol conjugate addition copper catalyst. Let’s learn more about this compound (cas:75732-01-3).
A direct catalytic asym. intramol. conjugate addition of thioamide to α,β-unsaturated esters is reported. Catalytic generation of a thioamide enolate with a soft Lewis acid/hard Bronsted base cooperative catalyst was the key to the efficient catalysis. A mesitylcopper/(S)-Xyl-P-Phos catalyst exhibited high catalytic performance.
Although many compounds look similar to this compound(75732-01-3)HPLC of Formula: 75732-01-3, numerous studies have shown that this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com