Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Mesitylcopper(I), is researched, Molecular C9H11Cu, CAS is 75732-01-3, about A heteroleptic tetranuclear copper amide/aryl complex: 1,4:2,3-bis(μ-2,4,6-trimethylphenyl-C,C)-1,2:3,4-bis[μ-bis(trimethylsilyl)amido-N,N]tetracopper(I).Related Products of 75732-01-3.
The title compound, [1,2:3,4-(CuBtsa)2-1,4:2,3-(CuMes)2] [Btsa is N(SiMe3)2; Mes is 2,4,6-Me3C6H2], was obtained as the product of a ligand redistribution between the GeII amide, GeBtsa2, and the CuI aryl, CuMes. The compound is triclinic, space group P1̅, with a 9.171(2), b 11.353(2), c 20.314(4) Å, α 101.98(1), β 94.56(2), γ 107.28(2)°; Z = 2, dc = 1.383; R = 0.037, Rw(F2) = 0.101 for 8527 reflections. It contains an almost planar eight-membered central ring, Cu4C2N2, with two-coordinate Cu atoms (average Cu-C 1.986, average Cu-N 1.936, average C-Cu-N 169.97°).
This literature about this compound(75732-01-3)Related Products of 75732-01-3has given us a lot of inspiration, and I hope that the research on this compound(Mesitylcopper(I)) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com