Synthetic Route of C9H11Cu. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Mesitylcopper(I), is researched, Molecular C9H11Cu, CAS is 75732-01-3, about Conjugate addition of diorganozincs to α,β-unsaturated ketones catalyzed by a copper(I)-sulfonamide combined system. Author is Kitamura, Masato; Miki, Takashi; Nakano, Keiji; Noyori, Ryoji.
In the presence of a Cu(I)-N-monosubstituted sulfonamide combined catalyst system, diorganozincs react with α,β-unsaturated ketones, e.g., 2-cycloheptenone, to generate Zn enolates, which may be hydrolyzed giving the β-substituted ketones, e.g., 3-ethylcycloheptanone, or used for further aldol reaction or Pd(0)-catalyzed reaction with allyl acetate leading to the regiospecific α,β-vicinal condensation products.
In addition to the literature in the link below, there is a lot of literature about this compound(Mesitylcopper(I))Synthetic Route of C9H11Cu, illustrating the importance and wide applicability of this compound(75732-01-3).
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com