Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 75732-01-3, is researched, SMILESS is [Cu]C1=C(C)C=C(C)C=C1C, Molecular C9H11CuJournal, Journal of Organometallic Chemistry called Insertion of formaldehyde into a copper-carbon bond, Author is Leoni, Piero; Pasquali, Marco, the main research direction is formaldehyde insertion copper carbon bond; mesitylcopper insertion formaldehyde.Application In Synthesis of Mesitylcopper(I).
Upon mixing equimolar amounts of mesitylcopper(I), CuAr, (Ar = 2,4,6-trimethylphenyl) and polymeric formaldehyde in THF in the presence of PPh3 the formaldehyde quickly dissolves. Gas-chromatog. anal. of the products after hydrolytic workup reveals the presence of mesityl alc., ArCH2OH (60% yield), the expected product of direct insertion of formaldehyde into a mesityl-copper bond. When the reaction is carried on for several days, 2,4,6-trimethylbenzyl formate and Me formate are the main products.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com