Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Chemical Science called Catalytic enantioselective synthesis of 2-(2-hydroxyethyl)indole scaffolds via consecutive intramolecular amido-cupration of allenes and asymmetric addition of carbonyl compounds, Author is Chikkade, Prasanna Kumara; Shimizu, Yohei; Kanai, Motomu, which mentions a compound: 75732-01-3, SMILESS is [Cu]C1=C(C)C=C(C)C=C1C, Molecular C9H11Cu, Application In Synthesis of Mesitylcopper(I).
A catalytic enantioselective method for the synthesis of 2-(2-hydroxyethyl)indole scaffolds was developed. The process included catalytic intramol. amido-cupration of an allene to generate a novel allylcopper species, followed by asym. addition of the thus-generated chiral nucleophile to aldehydes and ketones. This was the first example of catalytic indole formation coupled with asym. C-C bond formation via in situ generation of a reactive chiral allylcopper species.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com