The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Mesitylcopper(I)( cas:75732-01-3 ) is researched.Recommanded Product: 75732-01-3.Gustafsson, Bjorn; Hakansson, Mikael; Westman, Gunnar; Jagner, Susan published the article 《A tetrameric copper(I) alkoxide with a π-tethered ligand: 2-allyl-6-methylphenoxocopper(I)》 about this compound( cas:75732-01-3 ) in Journal of Organometallic Chemistry. Keywords: tetrameric copper alkoxide pi tethered ligand preparation crystal structure; allyl methylphenoxo copper tetrameric cubane type preparation crystal structure; mesitylcopper reaction allyl methylphenol. Let’s learn more about this compound (cas:75732-01-3).
The complex 2-allyl-6-methylphenoxocopper(I) has been prepared by reaction between mesitylcopper(I) and 2-allyl-6-methylphenol. Crystallog. studies show that the compound is tetrameric with a distorted cubane-type copper(I)-oxygen core, and with addnl. π-coordination of the ligand to copper through the alkene functionality (ν(C:C) = 1520 cm-1). The ligands thus act both as chelates and as bridges between adjacent copper(I) centers. Copper(I) exhibits trigonal pyramidal coordination geometry with Cu-C distances to the C:C group of 1.976(9) and 2.017(11) Å and Cu-O distances of 1.973(6), 2.021(6) and 2.577(6) Å, resp.
There is still a lot of research devoted to this compound(SMILES：[Cu]C1=C(C)C=C(C)C=C1C)Recommanded Product: 75732-01-3, and with the development of science, more effects of this compound(75732-01-3) can be discovered.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com