So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Bumagin, N. A.; Kalinovskii, I. O.; Beletskaya, I. P. researched the compound: Mesitylcopper(I)( cas:75732-01-3 ).Safety of Mesitylcopper(I).They published the article 《The palladium-catalyzed cross-coupling reactions of mesitylcopper with aryl iodides》 about this compound( cas:75732-01-3 ) in Journal of Organometallic Chemistry. Keywords: cross coupling reaction mesitylcopper; aryl iodide coupling mesitylcopper; biphenyl. We’ll tell you more about this compound (cas:75732-01-3).
Mesitylcopper reacts with aryl iodides p-IC6H4R (R = MeO, Cl, Ac, CN, NO2), containing both electron-withdrawing and electron-donating groups, in the presence of 1 equiv Bu4NX (X = Br, I) and 1 mol % of PhPdI(PPh3)2 to give cross-coupling products p-R1C6H4R (same R; R1 = mesityl) in high yields.
There is still a lot of research devoted to this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C)Safety of Mesitylcopper(I), and with the development of science, more effects of this compound(75732-01-3) can be discovered.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com