Davies, Robert P.; Hornauer, Stefan; White, Andrew J. P. published the article 《Models for the reactive states of homocuprates: syntheses, structures and reactivities of [Cu2Li2Mes4] and [Cu3LiMes4]》. Keywords: copper lithium tetranuclear mesityl metallacycle preparation structure; crystal structure copper lithium tetranuclear mesityl metallacycle; mol structure copper lithium tetranuclear mesityl metallacycle; enone regioselective addition reaction copper lithium mesityl metallacycle promotion; DFT structure copper lithium tetranuclear mesityl metallacycle.They researched the compound: Mesitylcopper(I)( cas:75732-01-3 ).Recommanded Product: 75732-01-3. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:75732-01-3) here.
The synthesis and characterization (including x-ray crystallog.) of two novel tetranuclear and thermally-stable Li arylcuprates, [Cu2Li2Mes4] and [Cu3LiMes4], are reported. [Cu3LiMes4] is a highly active regioselective promoter for the 1,4-addition of organolithiums to enones (e.g. ≤96% conversion of cyclohex-2-enone to 3-butylcyclohexanone). DFT studies of 3 isomeric forms of [Cu2Li2Mes4] are reported.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com