So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Kitamura, Masato; Miki, Takashi; Nakano, Keiji; Noyori, Ryoji researched the compound: Mesitylcopper(I)( cas:75732-01-3 ).Recommanded Product: 75732-01-3.They published the article 《Conjugate addition of diorganozincs to α,β-unsaturated ketones catalyzed by a copper(I)-sulfonamide combined system》 about this compound( cas:75732-01-3 ) in Tetrahedron Letters. Keywords: addition conjugate diorganozinc ketone copper sulfonamide; cycloalkenone conjugate addition diorganozinc copper sulfonamide. We’ll tell you more about this compound (cas:75732-01-3).
In the presence of a Cu(I)-N-monosubstituted sulfonamide combined catalyst system, diorganozincs react with α,β-unsaturated ketones, e.g., 2-cycloheptenone, to generate Zn enolates, which may be hydrolyzed giving the β-substituted ketones, e.g., 3-ethylcycloheptanone, or used for further aldol reaction or Pd(0)-catalyzed reaction with allyl acetate leading to the regiospecific α,β-vicinal condensation products.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com