In the chemical reaction process, reaction time, type of solvent, can easily affect the result of the reaction, thereby determining the yield and properties of the reaction product. An updated downstream synthesis route of 7681-82-5 as follows. Recommanded Product: Sodium iodide
General procedure: Complexes 2 and 3 were synthesised by following a similar procedure as described for complex 1 but using anhydrous Cd(ClO4)2 (0.311g, 1mmol) and NaBr (0.101g, 1mmol) (For complex 2)/NaI (0.149g, 1mmol) (For complex 3) respectively instead of CdCl2 (0.183g, 1mmol). The needle shaped brown colored crystals of 2 and 3 were washed with a methanol-water mixture and dried in desiccator containing anhydrous CaCl2 and then characterized by elemental analysis, spectroscopic methods, and X-ray diffraction. Complex 2: Yield: 0.851g, 73.36% (with respect to CuL). Anal. Calc. for C50H40CdCu2Br2N4O4: C, 51.76; H, 3.48; N, 4.83. Found: C, 51.59; H, 3.41; N, 4.94%. IR (KBr pellet, cm-1): nu(C=N) 1603. UV/Vis: lambdamax(nm) [epsilonmax(M-1 cm-1)] in (DMF)=588(470), 383(29570), 313(62182). Complex 3: Yield: 0.910g, 72.56% (with respect to CuL). Anal. Calc. for C50H40CdCu2I2N4O4: C, 47.88; H, 3.21; N, 4.47. Found: C, 47.73; H, 3.07; N, 4.30%. IR (KBr pellet, cm-1): nu(C=N) 1602. UV/Vis: lambdamax(nm) [epsilonmax(M-1 cm-1)] in (DMF)=589(479), 382(38868), 313(81774).
According to the analysis of related databases, 7681-82-5, the application of this compound in the production field has become more and more popular.
Reference:
Article; Ganguly, Sayantan; Bauza, Antonio; Frontera, Antonio; Ghosh, Ashutosh; Inorganica Chimica Acta; vol. 492; (2019); p. 142 – 149;,
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com