A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Application In Synthesis of 1-Bromo-3-fluoro-2-iodobenzene, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 450412-29-0, Name is 1-Bromo-3-fluoro-2-iodobenzene, molecular formula is C6H3BrFI. In an article, author is Voronkov, M. G.,once mentioned of 450412-29-0.
Acyl iodides in organic synthesis: IX. Cleavage of the Si-O-C and Si-O-Si moieties
Reactions of acyl iodides RCOI (R = Me, Ph) with organosilicon compounds involve cleavage of the Si-O-C and Si-O-Si fragments. Acetyl iodide reacts with alkyl(alkoxy)silanes with evolution of heat, and cleavage of the Si-O bond results in the formation of oligo-or polysiloxanes, alkyl iodides, and alkyl acetates. 1,3-Diacetoxytetramethyldisiloxane is formed in the reaction of acetyl iodide with dimethoxy(dimethyl)silane. Acyl iodides readily react with 1-ethoxysilatrane to give 1-acyloxysilatranes as a result of cleavage of the C-O bond. The reaction of acetyl iodide with hexaethyldisiloxane yields triethylsilyl acetate and triethyliodosilane, while in the reaction with octamethyltrisiloxane iodo(trimethyl)silane and dimethyl(trimethylsiloxy)silyl acetate are obtained.
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