Discovery of Heptadecafluoro-1-iodooctane

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Carbonyl propargylation and allenylation with 2-propynyl mesylates, tin(IV) iodide, and tetrabutylammonium iodide controlled by either a steric effect or coordination effect

A combination of tin(IV) iodide and tetrabutylammonium iodide can be used for propargylation or allenylation of aldehydes with 2-propynyl mesylates in dichloromethane. 1-Methyl-2-propynyl mesylate or 2-butynyl mesylate results in propargylation or allenylation controlled by the steric effect of the 1- or 3-methyl group, and 3-trimethylsilyl-2-propynyl mesylate results in propargylation controlled by the coordination of triiodostannate to silane.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 507-63-1 help many people in the next few years. Name: Heptadecafluoro-1-iodooctane.