Carbonylation of aryl halides and vinyl bromides mediated by tetracarbonylcobalt anion was written by Miura, Masahiro;Akase, Fumiaki;Shinohara, Masato;Nomura, Masakatsu. And the article was included in Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) in 1987.Recommanded Product: 36748-88-6 This article mentions the following:
The reaction of aryl halides with octacarbonyldicobalt in the presence of Me iodide and sodium hydroxide under phase-transfer conditions gave a mixture of aryl Me ketones and aromatic carboxylic acids. For example, 1-bromonaphthalene gave 54% 1-acetonaphthone and 20% 1-naphthoic acid. From vinyl bromides the corresponding carboxylic acids were obtained exclusively. Thus, Ph2C:CHBr gave 80% Ph2C:CHCO2H. In the experiment, the researchers used many compounds, for example, 3-Iodobenzo[b]thiophene (cas: 36748-88-6Recommanded Product: 36748-88-6).
3-Iodobenzo[b]thiophene (cas: 36748-88-6) belongs to iodide derivatives. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles. Organoiodine lubricants can be used with titanium, stainless steels, and other metals which tend to seize up with conventional lubricants: organoiodine lubricants can be used in turbines and spacecraft, and as a cutting oil in machining.Recommanded Product: 36748-88-6
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com