Synthesis of optically active ring-A substituted tryptophans as IDO inhibitors was written by Li, Xiaoyan;Yin, Wenyuan;Sarma, P. V. V. Srirama;Zhou, Hao;Ma, Jun;Cook, James M.. And the article was included in Tetrahedron Letters in 2004.SDS of cas: 220185-63-7 This article mentions the following:
The first stereoselective synthesis of optically active 6-chloro-
4,5-Dichloro-2-iodoaniline (cas: 220185-63-7) belongs to iodide derivatives. Organic iodides are widely used in organic synthesis. Halogenation of aromatic hydrocarbons is a very important reaction via an electrophilic aromatic substitution. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I. This periodic order also follows the atomic radius of halogens and the length of the carbon-halogen bond.SDS of cas: 220185-63-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com