Regioirregular and catalytic Mizoroki-Heck reactions was written by Garnes-Portoles, Francisco;Greco, Rossella;Oliver-Meseguer, Judit;Castellanos-Soriano, Jorge;Consuelo Jimenez, M.;Lopez-Haro, Miguel;Hernandez-Garrido, Juan Carlos;Boronat, Mercedes;Perez-Ruiz, Raul;Leyva-Perez, Antonio. And the article was included in Nature Catalysis in 2021.Computed Properties of C7H6FIO This article mentions the following:
Here, the ligand-free, few-atom palladium clusters in solution catalyze the α-selective intramol. Mizoroki-Heck coupling of iodoaryl cinnamates, and mechanistic studies support the formation of a sterically encumbered cinnamate-palladium cluster intermediate was showed. Following this rationale, the α-selective intermol. coupling of aryl iodides with styrenes was also achieved with palladium clusters encapsulated within fine-tuned and sterically restricted zeolite cavities to produce 1,1-bisarylethylenes, which are further engaged with aryl halides by a metal-free photoredox-catalyzed coupling. These ligand-free methodologies significantly expand the chem. space of the Mizoroki-Heck coupling. In the experiment, the researchers used many compounds, for example, (5-Fluoro-2-iodophenyl)methanol (cas: 877264-43-2Computed Properties of C7H6FIO).
(5-Fluoro-2-iodophenyl)methanol (cas: 877264-43-2) belongs to iodide derivatives. In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. Organoiodine lubricants can be used with titanium, stainless steels, and other metals which tend to seize up with conventional lubricants: organoiodine lubricants can be used in turbines and spacecraft, and as a cutting oil in machining.Computed Properties of C7H6FIO
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com