Bottom-up synthesis of fully sp2 hybridized three-dimensional microporous graphitic frameworks as metal-free catalysts was written by Talapaneni, Siddulu Naidu;Kim, Jaehoon;Je, Sang Hyun;Buyukcakir, Onur;Oh, Jihun;Coskun, Ali. And the article was included in Journal of Materials Chemistry A: Materials for Energy and Sustainability in 2017.Electric Literature of C8H9IO2 This article mentions the following:
We report on the bottom-up synthesis of a fully sp2-hybridized nitrogenated three-dimensional microporous graphitic framework (3D-MGF) starting from a highly preorganized, saddle-shaped tetraphenylene derivative under ionothermal reaction conditions. The 3D-MGF showed high stability and a surface area of 928 m2 g-1 along with a narrow pore size distribution. Our approach enabled template-free inclusion of the third dimension into the graphitic frameworks while retaining π-conjugation and conductivity, which was verified by their activity as metal-free electrocatalysts for the hydrogen evolution reaction. In the experiment, the researchers used many compounds, for example, 4-Iodo-1,2-dimethoxybenzene (cas: 5460-32-2Electric Literature of C8H9IO2).
4-Iodo-1,2-dimethoxybenzene (cas: 5460-32-2) belongs to iodide derivatives. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles. Iodo alkanes participate in a variety of organic synthesis reactions, which include the SimmonsSmith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.Electric Literature of C8H9IO2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com