Transition-Metal-Free Borylation of Alkyl Iodides via a Radical Mechanism was written by Liu, Qianyi;Hong, Junting;Sun, Beiqi;Bai, Guangcan;Li, Feng;Liu, Guoquan;Yang, Yang;Mo, Fanyang. And the article was included in Organic Letters in 2019.Recommanded Product: 1-Bromo-4-(2-iodoethyl)benzene This article mentions the following:
The authors describe an operationally simple transition-metal-free borylation of alkyl iodides. This method uses com. available diboron reagents as the B source and exhibits excellent functional group compatibility. Also, a diverse range of primary and secondary alkyl iodides could be effectively transformed to the corresponding alkylboronates in excellent yield. Mechanistic studies suggest that this borylation reaction proceeds through a single-electron transfer mechanism featuring the generation of an alkyl radical intermediate. In the experiment, the researchers used many compounds, for example, 1-Bromo-4-(2-iodoethyl)benzene (cas: 85356-68-9Recommanded Product: 1-Bromo-4-(2-iodoethyl)benzene).
1-Bromo-4-(2-iodoethyl)benzene (cas: 85356-68-9) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.Recommanded Product: 1-Bromo-4-(2-iodoethyl)benzene
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com