A Domino Approach (Hydrolysis/Dehydrohalogenation/Heck Coupling) for the Synthesis of Styrene Sulfonate Salts was written by Prakash, G. K. Surya;Jog, Parag V.;Krishnan, Hema S.;Olah, George A.. And the article was included in Journal of the American Chemical Society in 2011.Formula: C10H12I2 This article mentions the following:
A domino approach of hydrolysis/dehydrohalogenation/Heck coupling was used to synthesize styrene sulfonate salts from iodoarenes and chloroethanesulfonyl chloride in good to excellent yields. Methodol. was applicable for heterocyclic as well as disubstituted iodoarenes. Some of the key features of this synthetic methodol. include the use of a phosphine-free catalytic system, water as an environmentally friendly solvent, short reaction times, and absence of additives. In the experiment, the researchers used many compounds, for example, 1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1Formula: C10H12I2).
1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond.Formula: C10H12I2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com