Enantioselective Electrochemical Lactonization Using Chiral Iodoarenes as Mediators was written by Gao, Wen-Chao;Xiong, Zi-Yue;Pirhaghani, Shafigh;Wirth, Thomas. And the article was included in Synthesis in 2019.Synthetic Route of C8H7IO4 This article mentions the following:
The enantioselective electrochem. lactonization of diketo acid derivatives using chiral iodoarenes as redox mediators is reported for the first time. Good to high stereoselectivities are observed in the lactonization and also in intermol. α-alkoxylations of diketo ester derivatives This enantioselective process was then adapted to an electrochem. flow microreactor where only small amounts of supporting electrolyte were necessary. In the experiment, the researchers used many compounds, for example, Methyl 3,5-dihydroxy-4-iodobenzoate (cas: 338454-02-7Synthetic Route of C8H7IO4).
Methyl 3,5-dihydroxy-4-iodobenzoate (cas: 338454-02-7) belongs to iodide derivatives. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond.Synthetic Route of C8H7IO4
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com