Active Molybdenum-Based Anode for Dehydrogenative Coupling Reactions was written by Beil, Sebastian B.;Mueller, Timo;Sillart, Sydney B.;Franzmann, Peter;Bomm, Alexander;Holtkamp, Michael;Karst, Uwe;Schade, Wolfgang;Waldvogel, Siegfried R.. And the article was included in Angewandte Chemie, International Edition in 2018.Product Details of 5460-32-2 This article mentions the following:
A new and powerful active anode system that can be operated in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) was discovered. In HFIP the Mo anode forms a compact, conductive, and electroactive layer of higher-valent Mo species. This system can replace powerful but stoichiometrically required MoV reagents for the dehydrogenative coupling of aryls. This electrolytic reaction is more sustainable and allows the conversion of a broad scope of activated arenes. In the experiment, the researchers used many compounds, for example, 4-Iodo-1,2-dimethoxybenzene (cas: 5460-32-2Product Details of 5460-32-2).
4-Iodo-1,2-dimethoxybenzene (cas: 5460-32-2) belongs to iodide derivatives. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. The C–I bond is the weakest of the carbon–halogen bonds. These bond strengths correlate with the electronegativity of the halogen, decreasing in the order F > Cl > Br > I.Product Details of 5460-32-2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com