Rational Design of a Novel Mononuclear Rhodium(II) Complex was written by Dixon, Felicia M.;Farrell, Joshua R.;Doan, Peter E.;Williamson, Amanda;Weinberger, Dana A.;Mirkin, Chad A.;Stern, Charlotte;Incarvito, Christopher D.;Liable-Sands, Louise M.;Zakharov, Lev N.;Rheingold, Arnold L.. And the article was included in Organometallics in 2002.Recommanded Product: 3268-21-1 This article mentions the following:
Reaction of rhodium(I) with a multidentate hemilabile bisphosphine ligand yields a two-legged piano-stool complexes I (X = O, n = 1,2; X = CH2, n = 2) whose steric and electronic factors stabilize rhodium(II) upon chem. oxidation The inherent stabilizing properties of the ligand system allow for the first structural isolation of a novel mononuclear organometallic rhodium(II) complex in a two-legged piano-stool geometry. The crystal structures of I (X = O, CH2, n = 2) and the oxidized product of I (X = CH2, n = 2) were determined In the experiment, the researchers used many compounds, for example, 1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1Recommanded Product: 3268-21-1).
1,4-Diiodo-2,3,5,6-tetramethylbenzene (cas: 3268-21-1) belongs to iodide derivatives. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics. A typical method for synthesis of aromatic iodides is diazotization of primary aromatic amines followed by treatment of potassium iodide. Aliphatic alcohols are converted to alkyl iodides by treating with hydrogen iodide.Recommanded Product: 3268-21-1
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com