Reddy, C. B. Rajashekar’s team published research in ChemistryOpen in 4 | CAS: 53279-83-7

ChemistryOpen published new progress about 53279-83-7. 53279-83-7 belongs to iodides-buliding-blocks, auxiliary class Iodide,Amine,Benzene,Alcohol, name is (2-Amino-5-iodophenyl)methanol, and the molecular formula is C7H8INO, Application of (2-Amino-5-iodophenyl)methanol.

Reddy, C. B. Rajashekar published the artcileChemoselective oxidation of benzyl, amino and propargyl alcohols to aldehydes and ketones under mild reaction conditions, Application of (2-Amino-5-iodophenyl)methanol, the publication is ChemistryOpen (2015), 4(2), 107-110, database is CAplus and MEDLINE.

An efficient, aerobic, chemoselective and simplified approach for the oxidation of a broad range of benzyl and propargyl alcs. containing diverse functional groups to their corresponding aldehydes and ketones in excellent yields under mild reaction conditions was reported. Optimal yields were obtained at room temperature using 1 mmol substrate, 10 mol% copper(I) iodide, 10 mol% 4-dimethylaminopyridine (DMAP) and 1 mol% 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) in acetonitrile under an oxygen balloon. The catalytic system can be applied even when sensitive and oxidizable groups such as alkynes, amines and phenols are present and also starting materials and products containing such groups were found to be stable under the developed conditions.

ChemistryOpen published new progress about 53279-83-7. 53279-83-7 belongs to iodides-buliding-blocks, auxiliary class Iodide,Amine,Benzene,Alcohol, name is (2-Amino-5-iodophenyl)methanol, and the molecular formula is C7H8INO, Application of (2-Amino-5-iodophenyl)methanol.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com