Mannancherry, Rajesh published the artcileMolecular dynamic staircases: all-carbon axial chiral “Geländer” structures, Name: Dimethyl 2-iodoterephthalate, the publication is Chemical Science (2018), 9(26), 5758-5766, database is CAplus and MEDLINE.
Herein, the syntheses of two tightly packed all-carbon “Geländer” mols. with axial chirality are described. Motivated by our previous results, we further reduced the bridge length by excluding the heteroatoms. The absolute configuration was determined by comparison of the measured and calculated CD (CD) spectra and the thermodn. stability was determined by dynamic high-performance liquid chromatog. (HPLC) and CD anal. The cyclophanes were fully characterized by CD measurements, X-ray diffraction (XRD) anal., NMR, UV-Vis and high resolution mass spectrometry (HRMS). Our novel all-carbon macrocycle is the most stable Geländer system reported so far.
Chemical Science published new progress about 165534-79-2. 165534-79-2 belongs to iodides-buliding-blocks, auxiliary class Iodide,Benzene,Ester, name is Dimethyl 2-iodoterephthalate, and the molecular formula is C10H9IO4, Name: Dimethyl 2-iodoterephthalate.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com