Bousrez, Guillaume published the artcileReady Access to Anhydrous Anionic Lanthanide Acetates by Using Imidazolium Acetate Ionic Liquids as the Reaction Medium, COA of Formula: C6H13I, the publication is Chemistry – A European Journal (2021), 27(52), 13181-13189, database is CAplus and MEDLINE.
Access to lanthanide acetate coordination compounds is challenged by the tendency of lanthanides to coordinate water and the plethora of acetate coordination modes. A straightforward, reproducible synthetic procedure by treating lanthanide chloride hydrates with defined ratios of the ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate ([C2mim][OAc]) has been developed. This reaction pathway leads to two isostructural crystalline anhydrous coordination complexes, the polymeric [C2mim]n[{Ln2(OAc)7}n] and the dimeric [C2mim]2[Ln2(OAc)8], based on the ion size and the ratio of IL used. A reaction with an IL : Ln-salt ratio of 5 : 1, where Ln = Nd, Sm, and Gd, led exclusively to the polymer, while for the heaviest lanthanides (Dy-Lu) the dimer was observed Reaction with Eu and Tb resulted in a mixture of both polymeric and dimeric forms. When the amount of IL and/or the size of the cation was increased, the reaction led to only the dimeric compound for all the lanthanide series. Crystallog. analyses of the resulting salts revealed three different types of metal-acetate coordination modes where η2μκ2 is the most represented in both structure types.
Chemistry – A European Journal published new progress about 638-45-9. 638-45-9 belongs to iodides-buliding-blocks, auxiliary class Iodide,Aliphatic hydrocarbon chain, name is 1-Iodohexane, and the molecular formula is C6H13I, COA of Formula: C6H13I.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com