De Valk, J. published the artcilePyrimidines from this laboratory. XXXI. ANRORC [addition nucleophile ring opening ring closing] mechanism. V. Occurrence of the ANRORC [addition nucleophile ring opening ring closing] mechanism in aminations of substituted haloaza-aromatics with potassium amide in liquid ammonia, Formula: C10H7IN2, the publication is Recueil des Travaux Chimiques des Pays-Bas (1973), 92(3), 442-8, database is CAplus.
Evidence is presented that the amination of 4-chloro-2,6-diphenylpyrimidine with KNH2 in liquid ammonia into the corresponding 4-amino compound occurs to the extent of about 45% by the ANRORC mechanism. In the amination of the 4-iodo- and 4-fluoro derivatives of 2,6-diphenylpyrimidine however, the ANRORC mechanism is not operative at all. The amination of 5-bromo-4-chloro-2,6-diphenylpyrimidine into 4-amino-5-bromo-2,6-diphenylpyrimidine occurs to the extent of about 18% by the ANRORC mechanism. The synthesis of 5-bromo-4-chloro-2,6-diphenylpyrimidine-1(3)-15N and of the 4-fluoro, 4-chloro and 4-iodo derivatives of 2,6-diphenylpyrimidine-1(3)-15N is described.
Recueil des Travaux Chimiques des Pays-Bas published new progress about 41270-96-6. 41270-96-6 belongs to iodides-buliding-blocks, auxiliary class Pyrimidine,Iodide,Benzene,Immunology/Inflammation,MIF, name is 4-Iodo-6-phenylpyrimidine, and the molecular formula is C10H7IN2, Formula: C10H7IN2.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com