Month: November 2022

On September 13, 2004, Wei, Qian; Galoppini, Elena published an article.Name: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane The title of the article was Tripodal Ru(II) complexes with conjugated and non-conjugated rigid-rod bridges for semiconductor nanoparticles sensitization. And the article contained the following:

Three tripodal Ru(II)-polypyridyl complexes were synthesized as models to study long-range electron transfer in TiO2 semiconductor nanoparticle thin films, in particular to study the effect of the conjugation of the bridge containing the Ru complex and for distance-dependence studies. The tripodal sensitizers, which are 1,3,5,7-tetraphenyladamantane derivatives having three COOMe anchoring groups and one rigid-rod bridge substituted with a Ru(II) complex, are the longest prepared to date (Ru-to-footprint distance ∼24 Å). Two have a rigid-rod bridge made of two p-ethynylphenylene units (Ph-E)2 capped with a 4-(2,2′-bipyridyl) (bpy) ligand or a 5-(1,10-phenanthrolinyl) (phen) ligand for the Ru complex. The third tripod, which contains a bpy ligand for the Ru complex, has one bicyclo[2.2.2]octylene (Bco) unit in place of a p-phenylene (Ph) unit and is the first example of a tripodal sensitizer with a nonconjugated bridge. Solution absorption and fluorescence data of the three complexes are reported. Photophys. studies of the non-conjugated Bco-bridged complex on TiO2 are not reported. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Name: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

The Article related to ruthenium tripodal sensitizer conjugated nonconjugated bridge preparation fluorescence, conjugation effect ruthenium tripodal sensitizer rigid rod bridge, photophys ruthenium tripodal sensitizer conjugated nonconjugated bridge and other aspects.Name: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On January 31, 2022, Shen, Guodong; Lu, Qichao; Wang, Zeyou; Sun, Weiwei; Zhang, Yalin; Huang, Xianqiang; Sun, Manman; Wang, Zhiming published an article.Product Details of 1012882-90-4 The title of the article was Environmentally Friendly and Recyclable CuCl2 -Mediated C-S Bond Coupling Strategy Using DMEDA as Ligand, Base and Solvent. And the article contained the following:

An environment-friendly, recyclable and economic strategy was developed to synthesize diaryl chalcogenides by the CuCl2-catalyzed C-S bond-formation reaction via iodobenzenes and benzenethiols/1,2-diphenyldisulfanes using N,N’-dimethylethane-1,2-diamine (DMEDA) as ligand, base and solvent. For these reactions, especially the reactions of diiodobenzenes and aminobenzenethiols/disulfanediyldianilines, a range of substrates were compatible and gave the corresponding products in good to excellent yields. Both of the reagents in the catalytic system (CuCl2/DMEDA) were inexpensive, conveniently separable and recyclable for more than five cycles. The experimental process involved the reaction of Ethyl 5-chloro-2-iodobenzoate(cas: 1012882-90-4).Product Details of 1012882-90-4

The Article related to iodobenzene thiophenol copper catalyst carbon sulfur bond formation, diphenylsulfane preparation green chem, diiodobenzene diphenyldisulfane copper catalyst carbon sulfur bond formation, bisphenylsulfanyl benzene preparation green chem and other aspects.Product Details of 1012882-90-4

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On September 14, 2017, Janetka, James W.; Mydock-McGrane, Laurel published a patent.Quality Control of 5-Bromo-2-iodobenzotrifluoride The title of the patent was Preparation of C-glycoside compounds useful for treating urinary tract infection. And the patent contained the following:

The present invention relates to mannosides I, wherein Ar is aryl, heteroaryl; Y1 and Y2 are independently H, hydroxyl, alkoxy, amino; were prepared and are useful as inhibitors of FimH and methods for the treatment or prevention of urinary tract infection, bacterial infection, Crohn’s disease, and inflammatory bowel disease. Thus, glycoside II was prepared and tested for its hemagglutination (EC>90 = 0.006 μM) inhibition and as FimH inhibitor. The experimental process involved the reaction of 5-Bromo-2-iodobenzotrifluoride(cas: 364-12-5).Quality Control of 5-Bromo-2-iodobenzotrifluoride

The Article related to antibacterial antagonist hemagglutination urinary tract infection glycoside preparation mannoside, alkyne azide cycloaddition suzuki coupling fimh inhibitor human antibiotic, triazole click preparation c glycoside urinary tract infection and other aspects.Quality Control of 5-Bromo-2-iodobenzotrifluoride

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

On September 30, 2019, Chhanda, Sadia Afrin; Itsuno, Shinichi published an article.Computed Properties of 144970-30-9 The title of the article was Design and synthesis of chiral hyperbranched polymers containing cinchona squaramide moieties and their catalytic activity in the asymmetric Michael addition reaction. And the article contained the following:

Chiral hyperbranched polymers (HBP) containing cinchona alkaloids were synthesized using a Mizoroki-Heck (MH) coupling polymerization reaction between a cinchona squaramide dimer and tri- or tetra-substituted aromatic iodides. This was a new type of polymeric chiral organocatalyst. We found that the as-obtained chiral HBPs show excellent catalytic activity in the asym. Michael reaction. Almost perfect enantioselectivity (>99% ee) was achieved in the reaction of β-ketoester and trans-β-nitrostyrene. The three-dimensional network structure of the chiral HBPs is structurally robust and can be reused for further reaction without any loss in their catalytic activity. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Computed Properties of 144970-30-9

The Article related to cinchona squaramide iodoarene copolymer preparation recyclability, keto ester nitro vinylarene chiral polymer organocatalyst michael addition, alkyl aryl nitroalkyl oxo cyclopentanecarboxylate diastereoselective enantioselective preparation and other aspects.Computed Properties of 144970-30-9

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Boldog, Ishtvan; Domasevitch, Konstantin; MacLaren, Jana K.; Heering, Christian; Makhloufi, Gamall; Janiak, Christoph published an article in 2014, the title of the article was A fluorite isoreticular series of porous framework complexes with tetrahedral ligands: new opportunities for azolate PCPs.Recommanded Product: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane And the article contains the following content:

Three porous coordination polymers with a simplified formula of [M4(μ4-Cl)L2]·nGuest (M = Cu, Cd) based on two adamantane-derived tetrahedral tetrazolate ligands, 1,3,5,7-tetrakis(tetrazol-5-yl)adamantane and 1,3,5,7-tetrakis(tetrazol-5-ylphenyl)adamantane, were synthesized. Along with one known representative (with tetrakis(tetrazol-5-ylphenyl)methane), the compounds establish a new isoreticular series with fluorite as the underlying net. The experimental process involved the reaction of 1,3,5,7-Tetrakis(4-iodophenyl)adamantane(cas: 144970-30-9).Recommanded Product: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

The Article related to isoreticular adamantane based tetrahedral tetrazolate copper cadmium mof preparation, crystal structure isoreticular adamantane based tetrazolate copper cadmium mof, gas adsorption adamantane based tetrahedral tetrazolate copper cadmium mof and other aspects.Recommanded Product: 1,3,5,7-Tetrakis(4-iodophenyl)adamantane

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com