Nauroozi, Djawed published the artcileSynthesis and solvent-free polymerisation of vinyl terephthalate for application as an anode material in organic batteries, Related Products of iodides-buliding-blocks, the publication is RSC Advances (2016), 6(112), 111350-111357, database is CAplus.
The synthesis and polymerization of di-Me 2-vinylterephthalate M1 for possible applications as an anode material in organic secondary batteries are reported. M1 exhibits a vinyl group as a polymerisable unit while the carboxylate moieties serve as cation (Li+, Na+) coordinating sites. The gram-scale synthesis of M1 is described via three different routes in order to evaluate the route with the highest overall yield. Furthermore, different conditions for free radical polymerization are investigated for obtaining polymer P1 with high mol. weights in order to study the impact of immobilizing the carboxylate redox-active centers in a polymer on the charge/discharge cycling stability when used in an organic battery. In order to synthesis suitable materials for battery investigations, P1 was post-functionalised to the corresponding lithium salt P1-Li, which was further electrochem. investigated. Cyclic voltammetry measurements showed for P1-Li redox activity in the range of 0.5-1.2 V vs. Li+/Li which assigns it as a candidate for the anode. Under the present exptl. conditions, the galvanostatic measurements of P1-Li exhibited a specific capacity of 64 mA h g-1. It is further demonstrated that P1-Li shows an improved cycling stability of 83% discharge capacity remaining after 100 cycles compared to the parent monomer (44%).
RSC Advances published new progress about 165534-79-2. 165534-79-2 belongs to iodides-buliding-blocks, auxiliary class Iodide,Benzene,Ester, name is Dimethyl 2-iodoterephthalate, and the molecular formula is C10H9IO4, Related Products of iodides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com