Fialkov, Ya. A.’s team published research in Zhurnal Obshchei Khimii in 18 | CAS: 6443-90-9

Zhurnal Obshchei Khimii published new progress about 6443-90-9. 6443-90-9 belongs to iodides-buliding-blocks, auxiliary class Pyridines, name is Pyridine Iodochloride complex, and the molecular formula is C5H5ClIN, Safety of Pyridine Iodochloride complex.

Fialkov, Ya. A. published the artcilePhysicochemical investigation of the system iodine chloride-pyridine, Safety of Pyridine Iodochloride complex, the publication is Zhurnal Obshchei Khimii (1948), 1205-14, database is CAplus.

The elec. conductivity-concentration curves at both 35 and 50° showed maximum at about 8 mol.% pyridine. At 35° they rose from 4.82 × 10-3 ohm-1 for pure ICl to a maximum of 21.39 × 10-3, and then dropped to 3.37 × 10-3 ohm-1 at 34.65 mol.% pyridine. Thermal analysis revealed 2 compounds in the system, having formulas C5H5N.ICl and C5H5N.2ICl and m.ps. of 128.50 and 35.10°, resp. There are 3 eutectics with concentrations (in mol.% pyridine) and temperatures, resp., of 20.73, -6.30°; 35.11, 23.60°; and 98.90, -50.20°. Electrolysis studies indicated that the following reactions occur: C5H5N + ICl = (C5H5-N.I)+ + Cl. During electrolysis the reactions at the electrodes are: 2 (C5H5N.I)+ + 2e = 2C5H5N + I2, and 2Cl = Cl2 + 2e.

Zhurnal Obshchei Khimii published new progress about 6443-90-9. 6443-90-9 belongs to iodides-buliding-blocks, auxiliary class Pyridines, name is Pyridine Iodochloride complex, and the molecular formula is C5H5ClIN, Safety of Pyridine Iodochloride complex.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com