Wang, Yan’s team published research in Angewandte Chemie, International Edition in 55 | CAS: 606-55-3

Angewandte Chemie, International Edition published new progress about 606-55-3. 606-55-3 belongs to iodides-buliding-blocks, auxiliary class Quinoline,Salt, name is 1-Ethyl-2-methylquinolin-1-ium iodide, and the molecular formula is C15H21BO3, Application of 1-Ethyl-2-methylquinolin-1-ium iodide.

Wang, Yan published the artcileEnantioselective Rhodium-Catalyzed Dearomative Arylation or Alkenylation of Quinolinium Salts, Application of 1-Ethyl-2-methylquinolin-1-ium iodide, the publication is Angewandte Chemie, International Edition (2016), 55(11), 3776-3780, database is CAplus and MEDLINE.

A highly enantioselective rhodium(I)-catalyzed dearomative arylation or alkenylation of easily available N-alkylquinolinium salts is reported, thus providing an effective and practical approach to the synthesis of dihydroquinolines in up to 99% ee. This reaction tolerates a wide range of functional groups with respect to both the organic boronic acids and the quinoline starting materials. Moreover, the synthetic utility of this protocol is demonstrated in the formal asym. synthesis of bioactive tetrahydroquinoline and the total syntheses of (-)-angustureine and (+)-cuspareine.

Angewandte Chemie, International Edition published new progress about 606-55-3. 606-55-3 belongs to iodides-buliding-blocks, auxiliary class Quinoline,Salt, name is 1-Ethyl-2-methylquinolin-1-ium iodide, and the molecular formula is C15H21BO3, Application of 1-Ethyl-2-methylquinolin-1-ium iodide.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com