Soldatova, Natalia S. et al. published their research in Advanced Synthesis & Catalysis in 2021 | CAS: 139139-80-3

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. Moreover, it is known that it controls biofilm formation. However, the role of indole in the cell has not been fully elucidated.Formula: C19H22F3IO3S

Copper-Catalyzed Selective N-Arylation of Oxadiazolones by Diaryliodonium Salts was written by Soldatova, Natalia S.;Semenov, Artem V.;Geyl, Kirill K.;Baykov, Sergey V.;Shetnev, Anton A.;Konstantinova, Anna S.;Korsakov, Mikhail M.;Yusubov, Mekhman S.;Postnikov, Pavel S.. And the article was included in Advanced Synthesis & Catalysis in 2021.Formula: C19H22F3IO3S The following contents are mentioned in the article:

The method for copper-catalyzed N-arylation of diverse oxadiazolones I (R1 = cyclopropyl, Ph, 5-methylthiophen-2-yl, etc.) by diaryliodonium salts R2I+(R3)R4- (R2 = Ph, 3-(trifluoromethyl)phenyl, 4-nitrophenyl, etc.; R3 = Ph, 2,4,6-trimethoxyphenyl, 4-bromophenyl, etc.) under mild conditions in high yields (up to 92%) using available CuI as a catalyst was reported. The developed method allows utilizing both sym. and unsym. diaryliodonium salts bearing auxiliary groups such as 2,4,6-trimethoxyphenyl (TMP). The steric effects in aryl moieties determined the chemoselectivity of N- and O-arylation of the 1,2,4-oxadiazol-5(4H)-ones I. Mesityl-substituted diaryliodonium salts demonstrated the high potential as a selective arylation reagent. The structural study suggests that steric accessibility of N-atom in 1,2,4-oxadiazol-5(4H)-ones I impacts the arylation with sterically hindered diaryliodonium salts. The synthetic application of proposed method was also demonstrated on selective arylation of 1,3,4-oxadiazol-2(3H)-ones II and 3-(p-Tolyl)-1,2,4-oxadiazole-5-thiol. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. Moreover, it is known that it controls biofilm formation. However, the role of indole in the cell has not been fully elucidated.Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com