Wang, Jia-Wang published the artcileNickel-Catalyzed Switchable Site-Selective Alkene Hydroalkylation by Temperature Regulation, Product Details of C6H13I, the publication is Angewandte Chemie, International Edition (2022), 61(31), e202205537, database is CAplus and MEDLINE.
A nickel-catalyzed switchable site-selective alkene hydroalkylation was reported. The selection of reaction temperatures led to protocols that provide regiodivergent hydroalkylated products starting from a single alkene substrate. This protocol allowed the convenient synthesis of α- and β-branched protected amines, both of which are important to the fields of pharmaceutical chem. and biochem. In addition, enantioenriched β-branched alkylamines can be accessed in a catalytic asym. variant. Preliminary mechanistic studies indicate that the formation of a more stable nickelacycle provides the driving force of migration. The thermodn. and kinetic properties of different reduction elimination intermediates are responsible for the switchable site-selectivity.
Angewandte Chemie, International Edition published new progress about 638-45-9. 638-45-9 belongs to iodides-buliding-blocks, auxiliary class Iodide,Aliphatic hydrocarbon chain, name is 1-Iodohexane, and the molecular formula is C13H9FO2, Product Details of C6H13I.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com