Dorian, Andreas published the artcileIron-Catalyzed Halogen Exchange of Trifluoromethyl Arenes, Application of 5-Bromo-2-iodobenzotrifluoride, the publication is Chemistry – A European Journal (2021), 27(42), 10839-10843, database is CAplus and MEDLINE.
The facile production of ArCF2X and ArCX3 from ArCF3 using catalytic iron(III)halides is reported, which constitutes the first iron-catalyzed halogen exchange for non-aromatic C-F bonds. Theor. calculations suggest direct activation of C-F bonds by iron coordination. ArCX3 and ArCF2X products of the reaction are synthetically valuable due to their diversification potential. In particular, chloro- and bromodifluoromethyl arenes (ArCF2Cl, ArCF2Br resp.) provide access to a myriad of difluoromethyl arene derivatives (ArCF2R). To optimize for mono-halogen exchange, a statistical method called Design of Experiments was used. Optimized parameters were successfully applied to electron rich and electron deficient aromatic substrates, and to the late stage diversification of flufenoxuron, a com. insecticide. These methods are highly practical, being run at convenient temperatures and using inexpensive common reagents.
Chemistry – A European Journal published new progress about 364-12-5. 364-12-5 belongs to iodides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Bromide,Iodide,Benzene, name is 5-Bromo-2-iodobenzotrifluoride, and the molecular formula is C7H3BrF3I, Application of 5-Bromo-2-iodobenzotrifluoride.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com