Iridium and rhodium-catalyzed C-H activation and formyl arylation of benzaldehydes under chelation-assistance was written by Yang, Xifa;Wang, He;Zhou, Xukai;Li, Xingwei. And the article was included in Organic & Biomolecular Chemistry in 2016.Application of 1204518-02-4 The following contents are mentioned in the article:
Mild and efficient synthesis of benzophenones via Ir(III)- and Rh(III)-catalyzed, directing group-assisted formyl C-H arylation of benzaldehydes was developed using diaryliodonium salts, in which Rh(III) and Ir(III) catalysts exhibited a complementary substrate scope. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Application of 1204518-02-4).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. The indole subunit is an almost ubiquitous component of biologically active natural products, and its study has been the focus of research for decades.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Application of 1204518-02-4
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com