Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, first isolated in 1866, and it is commonly synthesized from phenylhydrazine and pyruvic acid, although several other procedures have been discovered.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Name: Bis(2,4,6-trimethylphenyl)iodonium triflate
Additive-free Pd-catalyzed C-2 arylation of tryptophan derivatives with diaryl-iodonium salts was written by Sun, Jian;Jlang, Jun;Heng, Pans;Li, Jianjun. And the article was included in Journal of Chemical Research in 2018.Name: Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:
An efficient, mild and Pd-catalyzed C-2 arylation of Fmoc-L-tryptophan (Fmoc = 9-fluorenylmethoxycarbonyl) with diaryl-iodonium salts has been developed, giving easy access to C-2 arylated tryptophan derivatives This protocol tolerates a variety of functional groups and proceeds smoothly in high yields without any additives. In addition, the chemoselective C-H arylation with unsym. salts is described. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Name: Bis(2,4,6-trimethylphenyl)iodonium triflate).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, first isolated in 1866, and it is commonly synthesized from phenylhydrazine and pyruvic acid, although several other procedures have been discovered.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Name: Bis(2,4,6-trimethylphenyl)iodonium triflate
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com