Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts was written by Sallio, Romain;Payard, Pierre-Adrien;Pakulski, Pawel;Diachenko, Iryna;Fabre, Indira;Berteina-Raboin, Sabine;Colas, Cyril;Ciofini, Ilaria;Grimaud, Laurence;Gillaizeau, Isabelle. And the article was included in RSC Advances in 2021.Application In Synthesis of Mesityl(p-tolyl)iodonium trifluoromethanesulfonate The following contents are mentioned in the article:
This work reports a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles e.g., PhCH(Me)CN using eco-friendly diaryliodonium salts as diphenyliodonium triflate, (4-bromophenyl)(2,4,6-trimethylphenyl)iodonium triflate, 2-thienyl-(phenyl)iodonium triflate, etc. and leading to N-arylacetamides e.g., PhCH(Me)C(O)NHPh. The method features high efficiency, broad substrate scope and good functional group tolerance. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Application In Synthesis of Mesityl(p-tolyl)iodonium trifluoromethanesulfonate).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. It is used in perfumery and in making tryptophan, an essential amino acid, and indoleacetic acid (heteroauxin), a hormone that promotes the development of roots in plant cuttings.Application In Synthesis of Mesityl(p-tolyl)iodonium trifluoromethanesulfonate
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com