tert-Butoxide mediated cascade desulfonylation/arylation/hydrolysis of cyclic sulfonyimines using diaryliodonium salts: synthesis of diaryl ether derivatives bearing a 2-aldehyde group was written by Qian, Xiaofei;Han, Jianwei;Wang, Limin. And the article was included in RSC Advances in 2016.Application of 139139-80-3 The following contents are mentioned in the article:
Cascades of cyclic sulfonylimines mediated by tBuOK with diaryliodonium salts giving the diaryl ethers in good yields were developed. Furthermore, bulky ortho-substituted diaryl ethers with an aldehyde group were obtained easily in comparision with metal-catalyzed protocols. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Application of 139139-80-3).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Application of 139139-80-3
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com