Copper-catalyzed synthesis of trifluoromethyl(hetero)arenes from di(hetero)aryl-位3-iodanes was written by Pandey, Vinay Kumar;Anbarasan, Pazhamalai. And the article was included in RSC Advances in 2016.Computed Properties of C17H18F3IO3S The following contents are mentioned in the article:
An efficient synthesis of trifluoromethylated (hetero)arenes were achieved through the regioselective copper-catalyzed trifluoromethylation of di(hetero)aryl-位3-iodanes, employing readily available trifluoromethyltrimethylsilane. The reaction worked well for both sym. and unsym. di(hetero)aryl-位3-iodanes with good regioselectivity and also tolerated diverse functional groups such as bromo, iodo, cyano, nitro, ester, ketone and enolizable ketone. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Computed Properties of C17H18F3IO3S).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Computed Properties of C17H18F3IO3S
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com