Metal-Free Arylation of Ethyl Acetoacetate with Hypervalent Diaryliodonium Salts: An Immediate Access to Diverse 3-Aryl-4(1H)-Quinolones was written by Monastyrskyi, Andrii;Namelikonda, Niranjan K.;Manetsch, Roman. And the article was included in Journal of Organic Chemistry in 2015.HPLC of Formula: 139139-80-3 The following contents are mentioned in the article:
A clean arylation protocol of Et acetoacetate was developed using hypervalent diaryliodonium salts under mild and metal-free conditions. The scope of the reaction, using sym. and unsym. iodonium salts with varying sterics and electronics, was examined Further, this method has been applied for the synthesis of antimalarial compound ELQ-300, which is currently in preclin. development. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3HPLC of Formula: 139139-80-3).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.HPLC of Formula: 139139-80-3
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com