Room temperature, metal-free synthesis of diaryl ethers with use of diaryliodonium salts was written by Jalalian, Nazli;Ishikawa, Eloisa E.;Silva, Luiz F.;Olofsson, Berit. And the article was included in Organic Letters in 2011.Quality Control of Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:
A fast, high-yielding synthesis of diaryl ethers with use of mild and metal-free conditions has been developed. The scope includes bulky ortho-substituted diaryl ethers, which are difficult to obtain by metal-catalyzed protocols. Halo-substituents, racemization-prone amino acid derivatives, and heteroaromatics are also tolerated. The methodol. is expected to be of high utility in the synthesis of complex mols. and in the pharmaceutical industry. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Quality Control of Bis(2,4,6-trimethylphenyl)iodonium triflate).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, first isolated in 1866, and it is commonly synthesized from phenylhydrazine and pyruvic acid, although several other procedures have been discovered. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.Quality Control of Bis(2,4,6-trimethylphenyl)iodonium triflate
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com