CuO-Catalyzed 1,3-Addition of Diaryliodonium Triflates to Diazo Esters for the Stereoselective Synthesis of Triflate-Substituted β-Aryloxyl Acrylates was written by Lin, Jia-Jia;Zhou, Jun;Wu, Panpan;Chen, Chao. And the article was included in European Journal of Organic Chemistry in 2019.Product Details of 139139-80-3 The following contents are mentioned in the article:
CuO-catalyzed 1,3-addition of diaryliodonium triflates to diazo esters was realized. This new strategy forms a series of triflate-substituted β-aryloxyl acrylate compounds with good tolerance of functional groups and excellent regioselectivity. Mild reaction conditions are enough, and strong acids or bases are not required. Easy manipulation and good step-economy are further advantages. The alkenyl triflate products can be further modified via cross-coupling reactions to generate derivatized products. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Product Details of 139139-80-3).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Product Details of 139139-80-3
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com