Refining boron-iodane exchange to access versatile arylation reagents was written by Karandikar, Shubhendu S.;Stuart, David R.. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2022.Reference of 1204518-02-4 The following contents are mentioned in the article:
Aryl(Mes)iodonium salts I (R = Ph, 4-chlorophenyl, furan-2-yl, 1-benzothiophen-2-yl, etc.), which are multifaceted aryl transfer reagents, are synthesized via boron-iodane exchange. Modification to both the nucleophilic (aryl borons) RBF3K and electrophilic (mesityl-λ3-iodane) reaction components results in improved yield and faster reaction time compared to previous conditions. Mechanistic studies reveal a pathway that is more like transmetalation than SEAr. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Reference of 1204518-02-4).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole produced by Proteus, Pseudomonas, Escherichia and other species was shown to be a growth promoting factor in Arabidopsis thaliana.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Reference of 1204518-02-4
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com