Copper-Catalyzed Oxidative Ring Closure of ortho-Cyanoanilides with Hypervalent Iodonium Salts: Arylation-Ring Closure Approach to Iminobenzoxazines was written by Aradi, Klara;Novak, Zoltan. And the article was included in Advanced Synthesis & Catalysis in 2015.Category: iodides-buliding-blocks The following contents are mentioned in the article:
A novel, highly modular synthetic methodol. with high functional group tolerance was developed for the construction of iminobenzoxazine derivatives from ortho-cyanoanilides and diaryliodonium triflates via an oxidative arylation-cyclization path. The reaction is supposed to involve the formation of highly active aryl-copper(III) species. In this novel transformation, copper(II) triflate was used as catalyst in 1,2-dichloroethane or Et acetate and the reaction takes place at 75 °C in 2-16 h. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Category: iodides-buliding-blocks).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Category: iodides-buliding-blocks
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com