Asymmetric synthesis of chiral sulfoximines via the S-arylation of sulfinamides was written by Aota, Yusuke;Kano, Taichi;Maruoka, Keiji. And the article was included in Journal of the American Chemical Society in 2019.SDS of cas: 1204518-02-4 The following contents are mentioned in the article:
Optically active sulfoximines are a promising substructure in me-dicinal chem. However, a methodol. for preparing chiral sulfoximines in a stereoselective manner has been underdeveloped. Herein, an asym. synthesis of chiral sulfoximines having an aryl group by the newly developed sulfur-selective arylation of easily accessible chiral sulfinamides is reported. The utility of the pre-sent method is demonstrated by the asym. synthesis of a key intermediate of a COX-2 inhibitor. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4SDS of cas: 1204518-02-4).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. It is used in perfumery and in making tryptophan, an essential amino acid, and indoleacetic acid (heteroauxin), a hormone that promotes the development of roots in plant cuttings.SDS of cas: 1204518-02-4
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com