Pd-catalyzed divergent trifluoroethylation and arylation of arylboronic acids by aryl(2,2,2-trifluoroethyl)iodonium triflates was written by Yang, Jing;Han, Qiu-Yan;Zhao, Cheng-Long;Dong, Tao;Hou, Zhi-Yuan;Qin, Hua-Li;Zhang, Cheng-Pan. And the article was included in Organic & Biomolecular Chemistry in 2016.Name: Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:
Highly electrophilic aryl(2,2,2-trifluoroethyl)iodonium triflates were used for the first time as trifluoroethyl and aryl transfer reagents in Pd-catalyzed functionalization of arylboronic acids. Electron-rich arylboronic acids reacted with aryl(2,2,2-trifluoroethyl)iodonium triflates in CH3CN in the presence of Pd2(dba)3 and K3PO4 at room temperature to provide trifluoroethyl arenes in up to 82% yield, while the reactions of both electron-rich and -poor arylboronic acids with triflates in DMF in the presence of Pd[P(t-Bu)3]2 and Cs2CO3 at 40° afforded arylation products in up to 99% yield. This tunable protocol allowed access to trifluoroethyl arenes or biaryls in good to excellent yields under mild conditions and without the addition of extra ligands. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Name: Bis(2,4,6-trimethylphenyl)iodonium triflate).
Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Name: Bis(2,4,6-trimethylphenyl)iodonium triflate
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com