A Meta-Selective Copper-Catalyzed C-H Bond Arylation was written by Phipps, Robert J.;Gaunt, Matthew J.. And the article was included in Science (Washington, DC, United States) in 2009.Name: Mesityl(p-tolyl)iodonium trifluoromethanesulfonate The following contents are mentioned in the article:
For over a century, chem. transformations of benzene derivatives were guided by the high selectivity for electrophilic attack at the ortho/para positions in electron-rich substrates and at the meta position in electron-deficient mols. The authors have developed a copper-catalyzed arylation reaction that, in contrast, selectively substitutes Ph electrophiles at the aromatic carbon-hydrogen sites meta to an amido substituent. This previously elusive class of transformation is applicable to a broad range of aromatic compounds This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Name: Mesityl(p-tolyl)iodonium trifluoromethanesulfonate).
Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.Name: Mesityl(p-tolyl)iodonium trifluoromethanesulfonate
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com